Chemical Science is the flagship journal of the Royal Society of Chemistry and publishes findings of exceptional significance from across the chemical sciences. It is a global journal for the discovery and reporting of breakthroughs in basic chemical research, communicated to a worldwide audience without barriers, through open access.
《化学科学》是英国皇家化学学会的旗舰期刊,发表了化学科学领域具有特殊意义的发现。它是一个全球性的期刊,用于发现和报告基础化学研究的突破,通过开放获取,无障碍地向世界各地的读者传播。
Photon-upconverting chiral liquid crystal: significantly amplified upconverted circularly polarized luminescence† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03806f
来源期刊:Chemical ScienceDOI:10.1039/c8sc03806f
A cell membrane-anchored fluorescent probe for monitoring carbon monoxide release from living cells† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03584a
来源期刊:Chemical ScienceDOI:10.1039/c8sc03584a
Controllably realizing elastic/plastic bending based on a room-temperature phosphorescent waveguiding organic crystal† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03135e
来源期刊:Chemical ScienceDOI:10.1039/c8sc03135e
Towards high energy density lithium battery anodes: silicon and lithium
来源期刊:Chemical ScienceDOI:10.1039/c9sc01201j
Bayesian semi-supervised learning for uncertainty-calibrated prediction of molecular properties and active learning
来源期刊:Chemical ScienceDOI:10.1039/C9SC00616H
Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H2 evolution† †Electronic supplementary information (ESI) available. CCDC 1868011. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc05143g
来源期刊:Chemical ScienceDOI:10.1039/C8SC05143G
Efficient cell surface labelling of live zebrafish embryos: wash-free fluorescence imaging for cellular dynamics tracking and nanotoxicity evaluation† †Electronic supplementary information (ESI) available: Experimental details, Fig. S1–S23. See DOI: 10.1039/c8sc04884c
来源期刊:Chemical ScienceDOI:10.1039/c8sc04884c
Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks† †Electronic supplementary information (ESI) available. CCDC 1936715–1936717. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc03348c
来源期刊:Chemical ScienceDOI:10.1039/c9sc03348c
A cationic polymethacrylate-copolymer acts as an agonist for β-amyloid and an antagonist for amylin fibrillation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05771k
来源期刊:Chemical ScienceDOI:10.1039/c8sc05771k
Reactivity control of a photocatalytic system by changing the light intensity† †Electronic supplementary information (ESI) available: Comprehensive experimental details, further mechanistic investigations, control experiments and application-related details. See DOI: 10.1039/c9sc04584h
来源期刊:Chemical ScienceDOI:10.1039/c9sc04584h
PEGylated rhenium nanoclusters: a degradable metal photothermal nanoagent for cancer therapy† †Electronic supplementary information (ESI) available: Photothermal conversion efficiency calculation, XPS spectra of Re nanoclusters, digital photographs and H&E images of major organs. See DOI: 10.1039/c9
来源期刊:Chemical ScienceDOI:10.1039/c9sc00729f
Telomerase and poly(ADP-ribose) polymerase-1 activity sensing based on the high fluorescence selectivity and sensitivity of TOTO-1 towards G bases in single-stranded DNA and poly(ADP-ribose)† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05770b
来源期刊:Chemical ScienceDOI:10.1039/c8sc05770b
Rare “Janus”-faced single-molecule magnet exhibiting intramolecular ferromagnetic interactions† †Electronic supplementary information (ESI) available: Spectroscopy data, crystallographic data and tables, and magnetism details. CCDC 1850963. For ESI and crystallographic data in CIF or other electroni
来源期刊:Chemical ScienceDOI:10.1039/c8sc04384a
Topologically immobilized catalysis centre for long-term stable carbon dioxide reforming of methane† †Electronic supplementary information (ESI) available: Demonstration procedure; experimental and characterization details. See DOI: 10.1039/c8sc04965c
来源期刊:Chemical ScienceDOI:10.1039/c8sc04965c
Manganese(ii) phosphate nanosheet assembly with native out-of-plane Mn centres for electrocatalytic water oxidation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03764g
来源期刊:Chemical ScienceDOI:10.1039/c8sc03764g
Uncovering two kinetic factors in the controlled growth of topologically distinct core–shell metal–organic frameworks† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc02576f
来源期刊:Chemical ScienceDOI:10.1039/c9sc02576f
Vinylphosphonites for Staudinger-induced chemoselective peptide cyclization and functionalization† †This work is dedicated to Prof. Ron Raines on the occasion of his 60th birthday. ‡ ‡Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc01345h
来源期刊:Chemical ScienceDOI:10.1039/C9SC01345H
Aminoazobenzene@Ag modified meshes with large extent photo-response: towards reversible oil/water removal from oil/water mixtures† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc00020h
来源期刊:Chemical ScienceDOI:10.1039/c9sc00020h
Annihilator dimers enhance triplet fusion upconversion† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03725f
来源期刊:Chemical ScienceDOI:10.1039/c8sc03725f
Thiahelicene-based inherently chiral films for enantioselective electroanalysis† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03337d
来源期刊:Chemical ScienceDOI:10.1039/c8sc03337d
Colloidal tectonics for tandem synergistic Pickering interfacial catalysis: oxidative cleavage of cyclohexene oxide into adipic acid† †Electronic supplementary information (ESI) available: Experimental data, procedure characterization methods and additional figures. See DOI: 10.1039/c8sc03345e
来源期刊:Chemical ScienceDOI:10.1039/c8sc03345e
Photoactive chlorin e6 is a multifunctional modulator of amyloid-β aggregation and toxicity via specific interactions with its histidine residues† †Electronic supplementary information (ESI) available: General details on the materials and methods, and any associated references and supporting scheme,
来源期刊:Chemical ScienceDOI:10.1039/c8sc01992d
Nickel-catalyzed hydroalkylation and hydroalkenylation of 1,3-dienes with hydrazones† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc04177j
来源期刊:Chemical ScienceDOI:10.1039/c9sc04177j
Regulating C–C coupling in thermocatalytic and electrocatalytic COx conversion based on surface science
来源期刊:Chemical ScienceDOI:10.1039/c9sc02014d
The role of halogens in the catalyst transfer polycondensation for π-conjugated polymers† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc04808h
来源期刊:Chemical ScienceDOI:10.1039/c8sc04808h
Picture of the wet electron: a localized transient state in liquid water† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05101a
来源期刊:Chemical ScienceDOI:10.1039/C8SC05101A
One metal is enough: a nickel complex reduces nitrate anions to nitrogen gas† †Electronic supplementary information (ESI) available. CCDC 1867435, 1867437 and 1867438. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc00717b
来源期刊:Chemical ScienceDOI:10.1039/C9SC00717B
Streptavidin interfacing as a general strategy to localize fluorescent membrane tension probes in cells† †Electronic supplementary information (ESI) available: Detailed procedures and results for all reported experiments. See DOI: 10.1039/c8sc03620a
来源期刊:Chemical ScienceDOI:10.1039/c8sc03620a
Widely applicable background depletion step enables transaminase evolution through solid-phase screening† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05712e
来源期刊:Chemical ScienceDOI:10.1039/c8sc05712e
Controlling nanoemulsion surface chemistry with poly(2-oxazoline) amphiphiles† †Electronic supplementary information (ESI) available: Fig. S1–S37, Table S1, supporting equations, detailed experimental procedures, characterization of 3–11, 14–17. See DOI: 10.1039/c8sc05735d
来源期刊:Chemical ScienceDOI:10.1039/c8sc05735d
Molecular multifunctionality preservation upon surface deposition for a chiral single-molecule magnet† †Electronic supplementary information (ESI) available: Full experimental details and additional data for all the characterizations presented in the main text. Crystallographic data (including struc
来源期刊:Chemical ScienceDOI:10.1039/c8sc04917c
Construction of supramolecular nanotubes from protein crystals† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc04167a
来源期刊:Chemical ScienceDOI:10.1039/c8sc04167a
Catalytic reduction of aryl trialkylammonium salts to aryl silanes and arenes† †Electronic supplementary information (ESI) available: Experimental details and copies of NMR spectra. See DOI: 10.1039/c9sc01083a
来源期刊:Chemical ScienceDOI:10.1039/c9sc01083a
Surface enhanced dynamic nuclear polarization solid-state NMR spectroscopy sheds light on Brønsted–Lewis acid synergy during the zeolite catalyzed methanol-to-hydrocarbon process† †Electronic supplementary information (ESI) available: Complete experimental procedure, supplementary NMR figures and an
来源期刊:Chemical ScienceDOI:10.1039/c9sc02215e
Catalytic farming: reaction rotation extends catalyst performance† †Electronic supplementary information (ESI) available: TEM catalyst characterization, graphs of conversions and yields and multiple product tables for several reaction rotations. See DOI: 10.1039/c8sc04188a
来源期刊:Chemical ScienceDOI:10.1039/c8sc04188a
Quo vadis niobium? Divergent coordination behavior of early-transition metals towards MOF-5† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc01553a
来源期刊:Chemical ScienceDOI:10.1039/c9sc01553a
Molecular basis of methylation and chain-length programming in a fungal iterative highly reducing polyketide synthase† †Electronic supplementary information (ESI) available: Including all experimental, bioinformatic and characterisation details. See DOI: 10.1039/c9sc03173a
来源期刊:Chemical ScienceDOI:10.1039/C9SC03173A
Synthesis and characterization of an unnatural boron and nitrogen-containing tryptophan analogue and its incorporation into proteins† †Electronic supplementary information (ESI) available. CCDC 1879929. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc05167d
来源期刊:Chemical ScienceDOI:10.1039/c8sc05167d
Benchmark selectivity p-xylene separation by a non-porous molecular solid through liquid or vapor extraction† †Electronic supplementary information (ESI) available. CCDC 1889509–1889512. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc02621e
来源期刊:Chemical ScienceDOI:10.1039/c9sc02621e
Acylation-coupled lipophilic induction of polarisation (Acyl-cLIP): a universal assay for lipid transferase and hydrolase enzymes† †Electronic supplementary information (ESI) available: Experimental materials and methods, additional Acyl-cLIP data, chemical structures, hit compound counter-screens,
来源期刊:Chemical ScienceDOI:10.1039/c9sc01785b
A macrocyclic oligofuran: synthesis, solid state structure and electronic properties† †Electronic supplementary information (ESI) available. CCDC 1892379. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc03247a
来源期刊:Chemical ScienceDOI:10.1039/c9sc03247a
Homochiral nanotubes from heterochiral lipid mixtures: a shorter alkyl chain dominated chiral self-assembly† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc00215d
来源期刊:Chemical ScienceDOI:10.1039/c9sc00215d
Electrochemical C–H bond activation via cationic iridium hydride pincer complexes† †Electronic supplementary information (ESI) available. CCDC 1935784, 1935785 and 1935786. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc03076j
来源期刊:Chemical ScienceDOI:10.1039/c9sc03076j
A transition-metal-free & diazo-free styrene cyclopropanation† †Electronic supplementary information (ESI) available. CCDC 1915890. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc02749a
来源期刊:Chemical ScienceDOI:10.1039/c9sc02749a
Designer artificial membrane binding proteins to direct stem cells to the myocardium† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc02650a
来源期刊:Chemical ScienceDOI:10.1039/c9sc02650a
A general approach for the site-selective modification of native proteins, enabling the generation of stable and functional antibody–drug conjugates† †Dedicated to Professor Jack Baldwin on the occasion of his 80th birthday. ‡ ‡Electronic supplementary information (ESI) available. See DOI: 10.1039/c
来源期刊:Chemical ScienceDOI:10.1039/c8sc04645j
Condensed ferric dimers for green photocatalytic synthesis of nylon precursors† †Electronic supplementary information (ESI) available: Additional data (Fig. S1–S13) and references, and appendix. See DOI: 10.1039/c9sc01253b
来源期刊:Chemical ScienceDOI:10.1039/c9sc01253b
A functional interplay between intein and extein sequences in protein splicing compensates for the essential block B histidine† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc01074a
来源期刊:Chemical ScienceDOI:10.1039/c8sc01074a
Correction: Controlling the preferential motion of chiral molecular walkers on a surface
来源期刊:Chemical ScienceDOI:10.1039/C9SC90124H
A simple vaporous probe with atomic-scale sensitivity to structural ordering and orientation of molecular assembly† †Electronic supplementary information (ESI) available: Additional details for the experiments and data analysis. See DOI: 10.1039/c9sc01656b
来源期刊:Chemical ScienceDOI:10.1039/c9sc01656b