Organometallics 是金属有机化学的旗舰期刊,在有机和无机化学之间架起了桥梁。该期刊发表文章、通讯、综述和指南(指导性概述),描述了合成、结构、键合、化学反应性和反应机制的研究及各种应用,包括催化剂设计和催化过程;主族、过渡金属、镧系和锕系金属化学;高分子科学和材料科学的合成方面以及生物有机金属化学。Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.For the purposes of this journal, an "organometallic" compound is defined as one in which there is a bonding interaction between one or more carbon atoms of an organic group or molecule and a main-group, transition, lanthanide, or actinide metal atom (or atoms). Following longstanding tradition, organic derivatives of the metalloids (such as boron, silicon, and the like) are included in this definition. Furthermore, manuscripts dealing with metal-containing compounds that do not have metal–carbon bonds will be considered if there is a close relationship between the subject matter and the principles and practice of organometallic chemistry.
《有机金属化学》是有机金属化学的旗舰期刊,记录了有机和无机化学这一最活跃的科学领域的进展。该杂志发表文章、通讯、评论和教程(教学概述),描述了合成、结构、键合、化学反应性和各种应用的反应机理的研究,包括催化剂设计和催化过程;主族、过渡金属、镧系和锕系金属化学;聚合物科学和材料科学的合成方面;和生物有机金属化学。
Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future.
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00720
N-Heterocyclic Germylene and Stannylene Catalyzed Cyanosilylation and Hydroboration of Aldehydes
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00673
Phosphine-Free Well-Defined Mn(I) Complex-Catalyzed Synthesis of Amine, Imine, and 2,3-Dihydro-1H-perimidine via Hydrogen Autotransfer or Acceptorless Dehydrogenative Coupling of Amine and Alcohol
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00131
Manganese-Based Catalysts with Varying Ligand Substituents for the Electrochemical Reduction of CO2 to CO
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00554
Dipyrromethene and β‑Diketiminate ZincHydride Complexes: Resemblances and Differences
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00334
Tetrahydrodibenzophenanthridine-Based Boron-Bridged Polycyclic Aromatic Hydrocarbons: Synthesis, Structural Diversity, and Optical Properties
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00853
Synthesis and Characterization of a Tripodal Tris(nitroxide) Aluminum Complex and Its Catalytic Activity toward Carbonyl Hydroboration
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00933
Associative Ligand Exchange and Substrate Activation Reactions by a Zero-Valent Cobalt Tetraisocyanide Complex
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00777
Synthesis, Characterization, and Theoretical Investigation of a Transition State Analogue for Proton Transfer during C–H Activation by a Rhodium-Pincer Complex
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00887
Nickel Complexes Based on Molybdopterin-like Dithiolenes: Catalysts for CO2 Electroreduction
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00655
Synthetic and Structural Studies of [FeFe]-Hydrogenase Models Containing a Butterfly Fe/E (E = S, Se, or Te) Cluster Core. Electrocatalytic H2 Evolution Catalyzed by [(μ-SeCH2)(μ-CH2NCH2Ph)]Fe2(CO)6
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00022
Thermodynamic Hydricity across Solvents: Subtle Electronic Effects and Striking Ligation Effects in Iridium Hydrides
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00278
Ir/Thioether–Carbene, −Phosphinite, and −Phosphite Complexes for Asymmetric Hydrogenation. A Case for Comparison
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00514
Low-Energy Electronic Transition in SiB Rings
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00804
Rhenium(I) Phosphazane Complexes for Electrocatalytic CO2 Reduction
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00138
Examining the factors that govern the regioselectivity in rhodium-catalyzed alkyne cyclotrimerization
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00347
The Synthesis, Structure, and H/D Exchange Reactions of Water-Soluble Half-Sandwich Ruthenium(II) Hydrides of Indenyl and Dihydropentalenyl
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00084
Molybdenum-Mediated Vinylidene Rearrangement of Internal Acylalkynes and Sulfonylalkynes
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00019
(Arylimido)niobium(V) Complexes Containing 2-Pyridylmethylanilido Ligand as Catalyst Precursors for Ethylene Dimerization That Proceeds via Cationic Nb(V) Species
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00017
Investigation of the Electronic Structure of Aryl-Bridged Dinuclear U(III) and U(IV) Compounds
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00794
Thermally Stable Half-Sandwich Benzhydryl Ln(II) (Ln = Sm, Yb) Complexes Supported by Sterically Demanding Carbazolyl and Fluorenyl Ligands
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00624
Application of Polysaccharide-Based Chiral HPLC Columns for Separation of Nonenantiomeric Isomeric Mixtures of Organometallic Compounds
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00819
How To Make Your Computational Paper Interesting and Have It Published
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00942
Disclosure of Some Obscure Mechanistic Aspects of the Copper-Catalyzed Click Reactions Involving N2 Elimination Promoted by the Use of Electron-Deficient Azides from a DFT Perspective
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00691
Fluoro-imidazopyridinylidene Ruthenium Catalysts for Cross Metathesis with Ethylene
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00469
Metal Catalyzed Synthesis of Dihydropyridobenzodiazepines
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00322
Addition of Thiols to Isocyanates Catalyzed by Simple Rare-Earth-Metal Amides: Synthesis of S-Alkyl Thiocarbamates and Dithiocarbamates
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00147
Highly Regio- and Stereoselective Tridentate NCNN Cobalt-Catalyzed 1,3-Diyne Hydrosilylation
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00602
General Synthesis and Optical Properties of N-Aryl-N′-Silyldiazenes
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00654
Enantioselective Carbene Insertion into O–Hof Phenols with Chiral Palladium/2,2′-Biimidazole Complexes
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00219
Iron-SNS and -CNS Complexes: Selective Caryl–S Bond Cleavage and Amine-Borane Dehydrogenation Catalysis
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00524
Metallopolymerization as a Strategy to Translate Ligand-Modulated Chemoselectivity to Porous Catalysts
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00162
Mixed Valence Pt(II),Pt(IV),Pt(II) Complexes from a Diplatinum(III) Synthon and Sulfur-Based Anions
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00096
Ethylene Polymerization with Ni(II) Diimine Complexes Generated from 8-Halo-1-naphthylamines: The Role of Equilibrating Syn/Anti Diastereomers in Determining Polymer Properties
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00649
Synthesis of Metal-Containing Poly(thiophene methines) via Solid- and Melt-State Polymerization and Their Related Applications as Highly Sensitive Ni2+ Chemosensors
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00830
Macrocycle Formation by Cooperative Selection at a Double-Sited Frustrated Lewis Pair
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00002
Substituent Effects on Reactions of [RhCl(COD)]2 with Diazoalkanes
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00889
An Information-Rich Graphical Representation of Catalytic Cycles
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00563
Copper or Silver-Mediated Oxidative C(sp 2 )–H/N–H Cross-Coupling of Phthalimide and HeterocyclicArenes: Access to N ‑Arylphthalimides
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00443
Alkylation of Rhodium Porphyrin Complexes with Primary Alcohols under Basic Conditions
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00454
Synthesis of Molybdenum(VI) Neopentylidene Neopentylidyne Complexes
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00412
Isolation and Characterization of a Homoleptic Tetramethylcobalt(III) Distorted Square-Planar Complex
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00387
XL-Xantphos: Design and Synthesis of a Mechanistic Probe of Xantphos O-Coordination in Catalytic Reactions
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00141
Synthesis of 4,5-Dihydropyrazoles via Palladium-Catalyzed Cyclization Reactions of β,γ-Unsaturated Hydrazones with Aryl Iodides
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00656
Rhodium-Catalyzed Alkenylation of Toluene Using 1-Pentene: Regioselectivity To Generate Precursors for Bicyclic Compounds
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00535
Vanadium-Catalyzed Cross Metathesis: Limitations and Implications for Future CatalystDesign
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00362
Reactivity Studies of a Bis(π‑η 5 :σ‑η 1 ‑benzofulvene)titaniumComplex Including Simultaneous N–H and C(sp 2 )–HActivation of Dibenzylamine
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00487
Trifluoromethyl-Substituted Benzocyclobutenone andBenzocyclobutenedione: The Structure Anomaly of (Benzocyclobutenedione)tricarbonylchromiumComplexes
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.9B00370
Study of a Competing Hydrodefluorination Reaction During the Directed ortho-Lithiation/Borylation of 2-Fluorobenzaldehyde
来源期刊:OrganometallicsDOI:10.1021/ACS.ORGANOMET.8B00730
Transition-Metal Complexes of Diphosphanes Containing the η7-Cycloheptatrienyl-η5-Cyclopentadienyl Titanium (Troticene) Sandwich Moiety
来源期刊:OrganometallicsDOI:10.1021/acs.organomet.9b00606