Macromolecules发表有关聚合物科学所有方面的原创性、基础性和有影响的研究。收录有关聚合物科学所有基本领域的原创研究,包括合成、聚合机理和动力学、化学改性、溶液/熔体/固态特性,以及有机、无机和天然聚合物的表面性质。收录的论文展示了创新的概念、实验方法/现象和理论/计算方法。Macromolecules publishes original, fundamental, and impactful research on all aspects of polymer science. Topics of interest include synthesis (e.g., controlled polymerizations, polymerization catalysis, post polymerization modification, new monomer structures and polymer architectures, and polymerization mechanisms/kinetics analysis); phase behavior, thermodynamics, dynamic, and ordering/disordering phenomena (e.g., self-assembly, gelation, crystallization, solution/melt/solid-state characteristics); structure and properties (e.g., mechanical and rheological properties, surface/interfacial characteristics, electronic and transport properties); new state of the art characterization (e.g., spectroscopy, scattering, microscopy, rheology), simulation (e.g., Monte Carlo, molecular dynamics, multi-scale/coarse-grained modeling), and theoretical methods. Renewable/sustainable polymers, polymer networks, responsive polymers, electro-, magneto- and opto-active macromolecules, inorganic polymers, charge-transporting polymers (ion-containing, semiconducting, and conducting), nanostructured polymers, and polymer composites are also of interest. Typical papers published in Macromolecules showcase important and innovative concepts, experimental methods/observations, and theoretical/computational approaches that demonstrate a fundamental advance in the understanding of polymers.
大分子出版关于聚合物科学各个方面的原创性、基础性和有影响力的研究。感兴趣的主题包括合成(例如,受控聚合、聚合催化、聚合后改性、新单体结构和聚合物构造、以及聚合机理/动力学分析);相行为、热力学、动力学,和有序/无序现象(例如,自组装、凝胶化、结晶、溶液/熔融/固态特性);结构和性质(例如,机械和流变性能、表面/界面特性、电子和传输性能);新的现有技术表征(例如,光谱学、散射、显微术、流变学),模拟(例如,蒙特卡罗、分子动力学、多尺度/粗粒度建模)和理论方法。可再生/可持续的聚合物、聚合物网络、响应性聚合物、电活性、磁活性和光活性大分子、无机聚合物、电荷传输聚合物(含离子的、半导体的和导电的)、纳米结构聚合物和聚合物复合材料也是感兴趣的。发表在《Macromolecules》上的典型论文展示了重要的创新概念、实验方法/观察结果和理论/计算方法,证明了对聚合物理解的根本性进步。
Controllable Fabrication of Poly(Arylene Ether Nitrile) Dielectrics for Thermal-Resistant Film Capacitors
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00799
Polybutadiene Vitrimers Based on Dioxaborolane Chemistryand Dual Networks with Static and Dynamic Cross-links
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b01288
Tuning Orientational Order of Highly Aggregating P(NDI2OD-T2) by Solvent Vapor Annealing and Blade Coating
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02176
Quantitative Adjustment to the Molecular Energy Parameter in the Lake–Thomas Theory of Polymer Fracture Energy
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02341
Colloidal Stable PIC Vesicles and Lamellae Enabled by Wavelength-Orthogonal Disulfide Exchange and Polymerization-Induced Electrostatic Self-Assembly
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00571
Deconvolution of the Effects of Binary Associationsand Collective Assemblies on the Rheological Properties of EntangledSide-Chain Supramolecular Polymer Networks
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00323
Effect of Tertiary Amines on the Photoinduced Electron Transfer-Reversible Addition–Fragmentation Chain Transfer (PET-RAFT) Polymerization
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b01493
Hierarchical Sticker and Sticky Chain Dynamics in Self-Healing Butyl Rubber Ionomers
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00159
Origami Inspired Mechanics: Measuring Modulus and Force Recovery with Bent Polymer Films
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02002
Organic Photocatalyst for ppm-Level Visible-Light-Driven Reversible Addition–Fragmentation Chain-Transfer (RAFT) Polymerization with Excellent Oxygen Tolerance
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00940
α-Ketoesters as Nonaromatic Photoinitiators for Radical Polymerization of (Meth)acrylates
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02640
Characterization of Hydrogen Bonding Formation and Breaking in Semiconducting Polymers under Mechanical Strain
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00145
Sonochemically Initiated RAFT Polymerization in Organic Solvents
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B01845
Dynamic Moduli Mapping of Silica-Filled Styrene─Butadiene Rubber Vulcanizate by Nanorheological Atomic Force Microscopy
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02258
Bisurea and Bisthiourea H-Bonding Organocatalysts for Ring-Opening Polymerization: Cues for the Catalyst Design
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b01875
RAFT dispersion polymerization in silicone oil
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00129
Nonmigratory Poly(vinyl chloride)- block-polycaprolactone Plasticizers and Compatibilizers Prepared by Sequential RAFT and Ring-Opening Polymerization (RAFT-T-ROP)
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02146
Molecular Orientation Distribution of Regenerated Cellulose Fibers Investigated with Polarized Raman Spectroscopy
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00520
Stretch-Induced α-to-β Crystal Transition and Lamellae Structural Evolution of Poly(butylene adipate-ran-terephthalate) Aliphatic–Aromatic Copolyester
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02011
Segmental α-Relaxation for the First Step and Sub-Rouse Modes for the Second Step in Enthalpy Recovery in the Glassy State of Polystyrene
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02125
Pseudo-Polyrotaxanes of Cyclodextrins with Direct and Reverse X-Shaped Block Copolymers: A Kinetic and Structural Study
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02509
Chain Conformation, Molecular Dynamics, and Thermal Properties of Poly(n-methylene 2,5-furanoates) as a Function of Methylene Unit Sequence Length
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B01320
Hierarchical Assemblies of Dendrimers Embedded in Networks of Lanthanide-Based Supramolecular Polyelectrolytes
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02480
Effect of the Heterogeneous Structure on Mechanical Properties for a Nanocellulose-Reinforced Polymer Composite
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b01866
Reactive Processing in Extrusion-Based 3D Printing to Improve Isotropy and Mechanical Properties
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B01178
Ring–Chain Competition in Supramolecular PolymerizationDirected by Molecular Recognition of the Bisporphyrin Cleft
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B01012
Interfacial Engineering of Thermoresponsive Microgel Capsules: Polymeric Wetting vs Colloidal Adhesion
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02323
Molecular Design Approach for Directed Alignment of Conjugated Polymers
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B01140
Rheological Scaling of Ionic-Liquid-Based Polyelectrolytes in Ionic Liquid Solutions
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02544
Polydispersity Effects on Interpenetration in Compressed Brushes
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02361
Molecular-Weight Distribution of Living Chains inPolystyrene Prepared by Reversible Addition–Fragmentation Chain-TransferPolymerization
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b01331
Approach for Introducing a Single Metal Complex into a Polymer Chain: Metallo-Chain Transfer Agents in CO2 or COS/Epoxide Copolymerization Processes
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00906
Investigation of Deformation Behavior of Thiourethane Elastomers Using In Situ X-ray Scattering, Diffraction, and Absorption Methods
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b00982
Internal Structure of Hyaluronic Acid Hydrogels Controlled by Iron(III) Ion–Catechol Complexation
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00889
Photo-cross-linkable polymer inks for solution-based OLED fabrication
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b02030
Hierarchical Scattering Function for Silica-Filled Rubbers under Deformation: Effect of the Initial Cluster Distribution
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b01751
Deep Eutectic Solvent Assisted Facile Synthesis of Lignin-Based Cryogel
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02279
Phase Behavior of Phasmidic Mesogen-Jacketed Liquid Crystalline Polymers Displaying Chain Bundling
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00687
Relative Size of the Polymer and Nanoparticle Controls Polymer Diffusion in All-Polymer Nanocomposites
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B02596
Tuning Metastability of Poly(3-hexyl thiophene) Solutions to Enable in Situ Atomic Force Microscopy Imaging of Surface Nucleation
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b01547
Main-Chain Stiffness of Cellulosic Bottlebrushes with Polystyrene Side Chains Introduced Regioselectively at the O-6 Position
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b01628
Bicontinuous Double-Diamond Structures Formed in TernaryBlends of AB Diblock Copolymers with Block Chains of Different Lengths
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00724
Mobility of Polymer-Tethered Nanoparticles in Unentangled Polymer Melts.
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.8b02138
Dynamics of Telechelic Ionomers with Distribution of Number of Ionic Stickers at Chain Ends
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.8B01776
Alternating Copolymerization of trans-Internal Epoxides and Cyclic Anhydrides Mediated by Dinuclear Chromium Catalyst Systems
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00989
Size-Based Characterization of Polysaccharides by Taylor Dispersion Analysis with Photochemical Oxidation or Backscattering Interferometry Detections
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00605
Precision, Tunable Deuterated Polyethylene via Polyhomologation
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00500
Selective Observation of Chemical Structures at Surface and Core Regions of Heat-treated Poly(Acrylonitrile) Films by Solid-State NMR Spectroscopy
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b01906
Dewetting Rheology for Determining Viscoelastic Properties of Nonequilibrated Thin Polymer Films
来源期刊:MacromoleculesDOI:10.1021/acs.macromol.9b01384
Spontaneous Chain Orientation of Aromatic PolyimidesEvolved during Thermal Imidization from Shear-Oriented Glassy LiquidCrystalline Precursors
来源期刊:MacromoleculesDOI:10.1021/ACS.MACROMOL.9B00953